Photoelectrodes of Cu2O with interfacial structure of topological insulator Bi2Se3contributes to selective photoelectrocatalytic reduction of CO2towards methanol

Alejandro Aranda-Aguirre, Julio Ojeda, Juliana Ferreirade Brito, Sergi Garcia-Segura, Mar a.Valnice Boldrin Zanoni, Hugo Alarcon

Producción científica: Contribución a una revistaArtículo (Contribución a Revista)revisión exhaustiva

27 Citas (Scopus)

Resumen

Artificial photosynthesis emerges as feasible solution to diminish CO2content in the atmosphere. Photoelectrocatalysis can diminish CO2concentration while generating useful resources such as methanol. Here an alternative multilayer photoelectrode of FTO/Cu/Bi2Se3-Se/Cu2O is developed to enhance selective reduction of CO2 towards methanol. A novel electrosynthetic approach is described as strategy to modulate the atomic composition of p-type bismuth selenide chalcogenide intralayer. This method enhanced performance and selectivity of n-type Cu2O photoelectrocatalysts. Alkaline pH conditions favored yield and selectivity towards methanol production from CO2. The formation of an n-p heterojunction affects the Cu2Operformance on CO2reduction. The novel engineered FTO/Cu/Bi2Se3-Se/Cu2O multilayer photoelectrodes allowed obtaining up to 4.5mM of methanol, which correspond to 3-fold higher concentration than conventional FTO/Cu2O electrodes reported in literature. Photoelectrodes of FTO/ Cu/Bi2Se3-Se/Cu2O overperform conventional Cu2O in terms of kinetics and selectivity towards methanol production.

Idioma originalInglés
Número de artículo101154
PublicaciónJournal of CO2 Utilization
Volumen39
DOI
EstadoPublicada - jul. 2020
Publicado de forma externa

Huella

Profundice en los temas de investigación de 'Photoelectrodes of Cu2O with interfacial structure of topological insulator Bi2Se3contributes to selective photoelectrocatalytic reduction of CO2towards methanol'. En conjunto forman una huella única.

Citar esto